Copper(II) oxalate and oxamate complexes (Journal article)

Novosad, J./ Messimeri, A. C./ Papadimitriou, C. D./ Veltsistas, P. G./ Woollins, J. D.


Reaction of Cu-II salts with phenanthroline and oxalate (ox) or oxamate (oxm) gives [Cu(phen)(ox)(H2O)] . H2O or [Cu(phen)(oxm)(H2O)] . H2O complexes while direct treatment of Cu-II salts with oxalate or oxamate gives [NH4](2)[Cu(ox)(2)] and [Cu(oxm)(2)(H2O)(2)] respectively. The X-ray structures of one example of each system, aquo-oxamato-phenanthroline-copper(II)-dihydrate and the polymeric ammonium-bis(aquo)-tetraoxalato-dicopper(II)-dihydrate, are reported.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
Keywords: x-ray structure,magnetic-properties,oxamic acid,mu-oxamido,ligands,crystal,bridges
URI: http://olympias.lib.uoi.gr/jspui/handle/123456789/10233
ISSN: 0340-4285
Link: <Go to ISI>://000089150700012
http://www.springerlink.com/content/m777k22216106796/fulltext.pdf
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

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