Copper(I) Complexes with Tri-Ortho-Tolylphosphine and Heterocyclic Thione Ligands - Crystal-Structures of [(Pyrimidine-2-Thione)(Tri-Ortho-Tolylphosphine)Copper(I) Chloride] and [(Pyridine-2-Thione)(Tri-Ortho-Tolylphosphine)Copper(I) Iodide] (Journal article)

Hadjikakou, S. K./ Aslanidis, P./ Karagiannidis, P./ Aubry, A./ Skoulika, S.


Copper(I) complexes of the general formula [Cu(totp)(L)X], where X = Cl, I; totp = tri-ortho-tolylphosphine; L = pyridine-2-thione (py2SH), pyrimidine-2-thione (pymtH), 1,3-thiazolidine-2-thione (tzdtH), 1-methyl-1,3-imidazole-2-thione (meimtH), benz-1,3-imidazoline-2-thione (bzimtH2) and quinoline-2-thione (qntH) were prepared and characterized by their IR, UV-Vis and H-1 NMR spectroscopic data. The behaviour of the complexes upon photolysis in chloroform solutions has been investigated. The structures of [Cu(totp)(pymtH)Cl] and [Cu(totp)(tzdtH)I] were determined by X-ray diffraction: [Cu(totp)(pymtH)Cl] crystallizes in the trigonal space group P3BAR with a = 22.433(4), b = 22.433(4), c = 9.526(3) angstrom, gamma = 120-degrees and Z = 6; [Cu(tzdtH)(totp)I] crystallizes in the monoclinic space group P2(1)/n with a = 17.111(2), b = 10.505(1), c = 14.823(1) angstrom, beta = 108.30(1)-degrees, Z = 4. In both complexes the coordination around Cu is approximately trigonal planar. Steric protection at the central metal by the three methyl groups neighbouring the donor phosphorus of the phosphine ligand is likely to explain the preferential formation of three-coordinate complexes.
Institution and School/Department of submitter: Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
Keywords: metal-complexes,triphenylphosphine
URI: http://olympias.lib.uoi.gr/jspui/handle/123456789/10224
ISSN: 0020-1693
Link: <Go to ISI>://A1992HW79200002
http://ac.els-cdn.com/S0020169300803436/1-s2.0-S0020169300803436-main.pdf?_tid=c7001b87f5f8025aebe2194583468a28&acdnat=1333030149_fb392b231578edf17155ac5eaefc6815
Publisher: Elsevier
Appears in Collections:Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

Files in This Item:
File Description SizeFormat 
Hadjikakou-1992-Copper(I) Complexes.pdf645.8 kBAdobe PDFView/Open    Request a copy



 Please use this identifier to cite or link to this item:
http://olympias.lib.uoi.gr/jspui/handle/123456789/10224
  This item is a favorite for 0 people.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.